NMR-STUDY (H-1,C-13,P-31) OF THE (C2H5)3-NPXN COMPOUNDS (X=CL,BR,I-N=0,1,2,3)

被引:8
作者
VANLINTHOUDT, JP
VANDENBERGHE, EV
VANDERKELEN, GP
机构
[1] Laboratory for General and Inorganic Chemistry-B, University of Gent, B-9000 Gent
关键词
D O I
10.1016/0584-8539(79)80082-3
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
The 1H, 13C and 31P NMR data are reported for the (C2H5)3-nPXn compounds (X = Cl, Br, I; n = 0, 1, 2, 3). The chemical shifts are interpreted in terms of inductive and through-space effects of the X substituents together with a rehybridization of the phosphorous atom. The results of the coupling constants are in good agreement with the chemical shifts. © 1979.
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页码:1307 / 1310
页数:4
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