A THERMALLY STABLE PEROXOCOPPER(II) COMPLEX WITH UNUSUAL MU(4)-COORDINATION OF THE PEROXO LIGAND

被引：46

作者：

REIM, J ^{[1
]}

KREBS, B ^{[1
]}

机构：

[1] UNIV MUNSTER,INST ANORGAN CHEM,D-48149 MUNSTER,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 19期

关键词：

D O I：

10.1002/anie.199419691

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stable at room temperature, the peroxocopper(II) cation in 1 (HL = 4‐methyl‐2,6‐bis(pyrrolidinomethyl)phenol) is a tetranuclear complex (the picture shows the central unit) that displays several unusual structural details, including a μ4‐bridging peroxo ligand. Peroxocopper(II) complexes are, in general, unstable compounds that can often be characterized only by spectroscopic methods at low temperatures. • equals; Cu, ○ = O, (Figure Presented.) = N. (Formula Presented.) (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：1969 / 1971

页数：3

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