RESONANT PHOTOEMISSION-STUDY OF THE ELECTRONIC-STRUCTURE OF K0.3MOO3

被引：8

作者：

BREUER, K ^{[1
]}

GOLDBERG, DM ^{[1
]}

SMITH, KE ^{[1
]}

GREENBLATT, M ^{[1
]}

MCCARROLL, W ^{[1
]}

机构：

[1] RUTGERS STATE UNIV,DEPT CHEM,NEW BRUNSWICK,NJ 08903

来源：

SOLID STATE COMMUNICATIONS | 1995年 / 94卷 / 08期

关键词：

SURFACES AND INTERFACES; POINT DEFECTS; ELECTRONIC BAND STRUCTURE; PHOTOELECTRON SPECTROSCOPIES; SYNCHROTRON RADIATION;

D O I：

10.1016/0038-1098(95)00143-3

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

We report resonant photoemission measurements performed on both stoichiometric and defective (20 ($) over bar 1) surfaces of the quasi-one dimensional oxide conductor K0.3MoO3. We investigate the resonant enhancement of the photoemission intensity in the O 2p band and of defect-related emission 2 eV below the Fermi level. The strong Fano-like resonance profile of the defect emission allows us to identify the defects as oxygen vacancies. The destructive nature of resonant photoemission for this system is revealed, as the core hole excitations that are necessary for the resonant photoemission process also lead to photon stimulated desorption.

引用

页码：601 / 606

页数：6

共 20 条

[1] RESONANT PHOTOEMISSION AND THE MECHANISM OF PHOTON-STIMULATED ION DESORPTION IN A TRANSITION-METAL OXIDE [J].