STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .37. EFFECT OF INCREASING ELECTRON DEMAND ON C-13 NUCLEAR MAGNETIC-RESONANCE SHIFTS IN THE 9-ARYL-EXO-5,6-TRIMETHYLENE AND 9-ARYL-ENDO-5,6-TRIMETHYLENE-9-NORBORNYL CARBOCATIONS - EFFECT OF THE CATIONIC CARBON CENTER ON REMOTE CARBON-ATOMS IN THE SKELETON AS REVEALED BY INCREASING ELECTRON DEMANDAR

被引：25

作者：

BROWN, HC

PERIASAMY, M

机构：

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1981年 / 46卷 / 16期

关键词：

D O I：

10.1021/jo00329a002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：3166 / 3170

页数：5

共 17 条

[1] ENDO-EXO-REARRANGEMENT IN THE ADDITION OF ACIDS TO DICYCLOPENTADIENE [J].

BARTLETT, PD ;

SCHNEIDER, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1946, 68 (01) :6-8

[2] THEORY OF LINEAR ELECTRIC-FIELD SHIFTS IN C-13 NUCLEAR MAGNETIC-RESONANCE [J].

BATCHELOR, JG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (12) :3410-3415

[3] CONVENIENT SYNTHETIC ROUTES TO 5,6-TRIMETHYLENENORBORNANONES [J].

BROWN, HC ;

ROTHBERG, I ;

VANDERJA.DL .

JOURNAL OF ORGANIC CHEMISTRY, 1972, 37 (25) :4098-4100

[4] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .36. EFFECT OF INCREASING ELECTRON DEMAND ON C-13 NUCLEAR MAGNETIC-RESONANCE SHIFTS IN THE 1-ARYL-1-CYCLOHEXYL AND 1-ARYL-1-CYCLOHEPTYL CARBOCATIONS - FURTHER TEST OF THE ABILITY OF THE SIGMA-C+ CONSTANTS TO CORRELATE C-13 NUCLEAR MAGNETIC-RESONANCE SHIFTS [J].

BROWN, HC ;

PERIASAMY, M .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (16) :3161-3165

[5] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .35. C-13 NUCLEAR MAGNETIC-RESONANCE STUDIES OF CARBOCATIONS - EFFECT OF INCREASING ELECTRON DEMAND ON THE C-13 NUCLEAR MAGNETIC-RESONANCE SHIFTS IN 2-ARYL-2-BUTYL AND 4-ARYL-4-HEPTYL CARBOCATIONS - CORRELATION OF THE DATA BY A NEW SET OF SUBSTITUENT CONSTANTS SIGMA-C+ [J].

BROWN, HC ;

PERIASAMY, M ;

LIU, KT .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (08) :1646-1650

[6] EVIDENCE FOR STERIC HINDRANCE TO IONIZATION IN SLOW RATES OF SOLVOLYSIS OF TERTIARY 2-,8-, AND 9-PHENYL-ENDO-5,6-TRIMETHYLENE-ENDO-NORBORNANYL P-NITROBENZOATES . AN UNUSUALLY HIGH EXO-ENDO RATE RATIO NOT INVOLVING SIGMA PARTICIPATION [J].

BROWN, HC ;

VANDERJA.DL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (24) :6850-&

[7] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .38. C-13 NUCLEAR MAGNETIC-RESONANCE STUDIES OF CARBOCATIONS .6. EFFECT OF INCREASING ELECTRON DEMAND ON THE CHEMICAL-SHIFTS OF THE ALPHA-CARBON ATOMS IN SUBSTITUTED ARYLDIALKYL CARBOCATIONS - CORRELATION OF THE DATA WITH A NEW SET OF SUBSTITUENT CONSTANTS, SIGMA-ALPHA-C+ [J].

BROWN, HC ;

KELLY, DP ;

PERIASAMY, M .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (16) :3170-3174

[8] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .34. C-13 NMR-STUDIES OF CARBOCATIONS .4. EFFECT OF INCREASING ELECTRON DEMAND ON THE C-13 NMR SHIFTS IN SUBSTITUTED TERT-CUMYL AND 1-ARYL-1-CYCLOPENTYL CARBOCATIONS - CORRELATION OF THE DATA BY A NEW SET OF SUBSTITUENT CONSTANTS, SIGMA-C+ [J].

BROWN, HC ;

KELLY, DP ;

PERIASAMY, M .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA-PHYSICAL SCIENCES, 1980, 77 (12) :6956-6960

[9] THE CHEMISTRY OF DICYCLOPENTADIENE .3. ADDITION OF ALCOHOLS AND PHENOLS [J].

BRUSON, HA ;

RIENER, TW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1946, 68 (01) :8-10

[10] STRUCTURAL-CHANGES IN 2-ARYLNORBORNYL AND OTHER ARYL CARBOCATIONS WITH INCREASING ELECTRON DEMAND - C-13 NUCLEAR MAGNETIC-RESONANCE AS A PROBE [J].

FARNUM, DG ;

BOTTO, RE ;

CHAMBERS, WT ;

LAM, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (12) :3847-3855

← 1 2 →