HIGH-ENERGY VIBRATIONAL OVERTONES OF POLYATOMIC-MOLECULES IN SOLIDS - INEQUIVALENT LOCAL C-H MODES AND SUBPICOSECOND DEPHASING OF NAPHTHALENE AT 1.3 K

被引：35

作者：

PERRY, JW

ZEWAIL, AH

机构：

[1] Arthur Amos Noyes Laboratory of Chemical Physic2 2 Contribution No. 5989., California Institute of Technology, Pasadena

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 65卷 / 01期

关键词：

D O I：

10.1016/0009-2614(79)80119-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report on the assignment of inequivalent C-H local modes in naphthalene by observation of overtones of symmetrically deuterated naphthalene (αd4) at low temperatures (1.3-2 K). Careful lineshape analysis gives information on the dephasing of these high-energy states as inferred from homogeneous linewidths. We observe new trends in the linewidths that suggest the relative importance of local-normal and local-local mode coupling. © 1979.

引用

页码：31 / 36

页数：6

共 30 条

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