CHIRAL ALCOHOL-INDUCED DIASTEREOSELECTIVE CONJUGATE ADDITION AND CYCLIZATION

被引：19

作者：

FANG, CL ^{[1
]}

SUEMUNE, H ^{[1
]}

SAKAI, K ^{[1
]}

机构：

[1] KYUSHU UNIV,FAC PHARMACEUT SCI,FUKUOKA 812,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 33期

关键词：

D O I：

10.1016/S0040-4039(00)97723-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Conjugate addition of organocuprate reagents to α,β-unsaturated esters of chiral trans-cyclohexanediol proceeded diastereoselectively, and the intramolecular trapping of the generated enolate also afforded asymmetric cyclization products. © 1990.

引用

页码：4751 / 4754

页数：4

共 8 条

[1]

NORMANT JF, 1983, CURRENT TRENDS ORGAN, P291

[2]

Posner G. H., 1980, INTRO SYNTHESIS USIN

[3] ALKYLATION OF ENOLATE IONS GENERATED REGIOSPECIFICALLY VIA ORGANOCOPPER REACTIONS - SYNTHESIS OF DECALIN SESQUITERPENE VALERANE AND OF PROSTAGLANDIN MODEL SYSTEMS [J].

POSNER, GH ;

STERLING, JJ ;

WHITTEN, CE ;

LENTZ, CM ;

BRUNELLE, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (01) :107-118

[4]

TAYLOR RJK, 1985, SYNTHESIS-STUTTGART, P364

[5] ORGANOCUPRATE ADDITION TO ALPHA, BETA-UNSATURATED COMPOUNDS - SYNTHETIC AND MECHANISTIC ASPECTS [J].

ULLENIUS, C ;

CHRISTENSON, B .

PURE AND APPLIED CHEMISTRY, 1988, 60 (01) :57-64

[6]

VERVIT L, 1972, J AM CHEM SOC, V101, P5143

[7]

WILHEIM RS, 1984, TETRAHEDRON, V40, P5005

[8] AN INSIGHT INTO THE ENANTIOSELECTIVE HYDROLYSES OF CYCLIC ACETATES CATALYZED BY PSEUDOMONAS-FLUORESCENS LIPASE [J].

XIE, ZF ;

NAKAMURA, I ;

SUEMUNE, H ;

SAKAI, K .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (14) :966-977

← 1 →