HEXANUCLEAR FERRIC COMPLEX WITH A NOVEL S = 5 GROUND-STATE
被引:22
作者:
HARVEY, DF
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机构:Department of Chemistry-0506, University of California at San Diego, La Jolla, California
HARVEY, DF
CHRISTMAS, CA
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机构:Department of Chemistry-0506, University of California at San Diego, La Jolla, California
CHRISTMAS, CA
MCCUSKER, JK
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机构:Department of Chemistry-0506, University of California at San Diego, La Jolla, California
MCCUSKER, JK
HAGEN, PM
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机构:Department of Chemistry-0506, University of California at San Diego, La Jolla, California
HAGEN, PM
CHADHA, RK
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机构:Department of Chemistry-0506, University of California at San Diego, La Jolla, California
CHADHA, RK
HENDRICKSON, DN
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机构:Department of Chemistry-0506, University of California at San Diego, La Jolla, California
HENDRICKSON, DN
机构:
[1] Department of Chemistry-0506, University of California at San Diego, La Jolla, California
来源:
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH
|
1991年
/
30卷
/
05期
关键词:
D O I:
10.1002/anie.199105981
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
The iron complex 1 shows novel, magnetic properties. Its spin ground state is S = 5, even though all six iron centers are high-spin Fe(III) ions. Magnetic measurements revealed an increase in mu-eff with decreasing temperature. Complex 1 was also characterized by X-ray structure analysis.