REACTION OF HYDROGEN-ATOMS WITH DIMETHYL SULFIDE

被引：30

作者：

YOKOTA, T ^{[1
]}

STRAUSZ, OP ^{[1
]}

机构：

[1] UNIV ALBERTA,HYDROCARBON RES CTR,DEPT CHEM,EDMONTON T6G 2G2,ALBERTA,CANADA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1979年 / 83卷 / 25期

关键词：

D O I：

10.1021/j100488a003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrogen atoms produced by the photolysis of H2S in the presence of a large excess of inert gas were reacted with CH3SCH3. A mechanism involving a short chain and the two novel elementary reactions H + CH3SCH3 → CH3SH + CH3 and HS + CH3SCH3 → CH3SSH + CH3 adequately explains all experimental observations. The rate coefficient of the former reaction was determined in the temperature range of 27-199°C to have the value (1.71 ± 0.26) × 1013 exp[-(2621 ± 88)/RT] cm3 mol-1 s-1 relative to the literature value for the H + H2S → SH + H2 reaction of (7.77 ± 0.90) × 1012 exp[-(1709 ± 60)/RT] cm3 mol-1 s-1. © 1979 American Chemical Society.

引用

页码：3196 / 3202

页数：7

共 26 条

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