TIN EFFECTS IN THE HYDROBORATION OF HINDERED OLEFINS

被引：3

作者：

AKERS, JA

BRYSON, TA

机构：

[1] Department of Chemistry, University of South Carolina, Columbia, SC

来源：

SYNTHETIC COMMUNICATIONS | 1990年 / 20卷 / 22期

关键词：

D O I：

10.1080/00397919008051588

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Intermolecular hydroboration of tetrasubstituted olefins is enhanced by allylic tin substituents. Intramolecular hydroboration using hindered allylic tin substrates is found to be inefficient presumably due to the steric bulk of the trialkylstannane group.

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页码：3453 / 3458

页数：6

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