SYNTHESIS OF ARENETRICARBONYLMANGANESE CATIONS AND HYDROGEN MIGRATIONS IN THE "CYCLOHEXADIENYLTRICARBONYLMANGANESE SERIES

被引：24

作者：

MUNRO, GAM ^{[1
]}

PAUSON, PL ^{[1
]}

机构：

[1] UNIV STRATHCLYDE,DEPT PURE & APPL CHEM,GLASGOW G1 1XL,SCOTLAND

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1979年 / 458卷 / 11期

关键词：

D O I：

10.1002/zaac.19794580128

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Improvements in the preparation of some arenetricarbonylmanganese cations and the preparation of (1,4‐dimethoxybenzene)tricarbonylmanganese hexafluorophosphate are described. Substitution of hydrocarbon groups into these complexes is possible via the known exo‐addition of organolithium reagents followed by thermal hydrogen‐shift and then hydride abstraction. The rearrangement is shown to involve migration of the 6‐endo hydrogen probably via a metal‐hydride intermediate. Copyright © 1979 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：211 / 218

页数：8

共 20 条

[1] CARBONYL HALIDES OF MANGANESE AND SOME RELATED COMPOUNDS [J].

ABEL, EW ;

WILKINSON, G .

JOURNAL OF THE CHEMICAL SOCIETY, 1959, (APR) :1501-1505

[2]

BENSON BC, 1971, Patent No. 1238961

[3] ELECTRONIC EFFECTS IN (CH3)NC6H6-NMN(CO)3 + COMPLEXES (N=0-6) AS EVIDENCED BY H-1 AND C-13 NMR-SPECTROSCOPY, MN-55 NQR SPECTROSCOPY, AND CARBONYL IR SPECTROSCOPY [J].

BRILL, TB ;

KOTLAR, AJ .

INORGANIC CHEMISTRY, 1974, 13 (02) :470-474

[4] CYCLOPENTADIENYL-AROMATIC SANDWICH COMPLEXES OF MANGANESE AND IRON [J].

COFFIELD, TH ;

SANDEL, V ;

CLOSSON, RD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (21) :5826-5826

[5] CYCLOHEPTATRIENE AND TROPYLIUM METAL-COMPLEXES .9. [1,5] HYDROGEN MIGRATIONS IN CYCLOHEPTATRIENES COMPLEXED TO CHROMIUM [J].

FOREMAN, MI ;

WATTS, WE ;

TODD, KH ;

PAUSON, PL ;

KNOX, GR .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1972, (09) :1141-&

[6]

GIRAITIS AP, 1962, Patent No. 3028220

[7]

JONES D, 1964, J CHEM SOC, P2479

[8] PI-CYCLOHEXADIENYL COMPOUNDS OF MANGANESE, RHENIUM, IRON, AND RUTHENIUM [J].

JONES, D ;

PRATT, L ;

WILKINSON, G .

JOURNAL OF THE CHEMICAL SOCIETY, 1962, (NOV) :4458-+

[9] DIENYL COMPLEXES OF TRANSITION METALS .4. STEREOCHEMISTRY OF ADDITION OF METHYL-LITHIUM AND OTHER NUCLEOPHILES TO ARENECYCLOPENTADIENYLIROON CATIONS AND OF HYDRIDE ABSTRACTION FROM RESULTING CYCLOHEXADIENYL COMPLEXES [J].

KHAND, IU ;

PAUSON, PL ;

WATTS, WE .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1969, (15) :2024-&

[10] A CONVENIENT SYNTHESIS OF DIMANGANESE DECACARBONYL FROM INEXPENSIVE STARTING MATERIALS AT ATMOSPHERIC PRESSURE [J].

KING, RB ;

STOKES, JC ;

KORENOWS.TF .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1968, 11 (03) :641-&

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