HIGHLY DIASTEREOSELECTIVE ADDITIONS OF ORGANOMETALLIC REAGENTS TO 1-O-SILYLATED 3,4-DI-O-BENZYL-L-ERYTHRULOSE DERIVATIVES

被引：17

作者：

CARDA, M

GONZALEZ, F

RODRIGUEZ, S

MARCO, JA

机构：

[1] UNIV VALENCIA,FAC QUIM,DEPT QUIM ORGAN,E-46100 BURJASSOT,SPAIN

[2] UNIV JAUME I,DEPT CIENCIAS EXPTL,E-12080 CASTELLON PLANA,SPAIN

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 08期

关键词：

D O I：

10.1016/S0957-4166(00)80421-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The diastereoselectivity of the addition of several organometallic reagents to the carbonyl group of the title compounds has been investigated, Some organomagnesium reagents display high diastereoselectivities (90-99%) and the major products are those predicted by the alpha-chelation model.

引用

页码：1799 / 1802

页数：4

共 8 条

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