ASYMMETRIC CATALYSIS .56. ENANTIOSELECTIVE HYDROSILYLATION OF ACETOPHENONE WITH A RHODIUM PICOLINEOXAZOLINE CATALYST 1-1

被引：37

作者：

BRUNNER, H

BRANDL, P

机构：

[1] Institut für Anorganische Chemie, Universität Regensburg, D-8400 Regensburg

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 390卷 / 03期

关键词：

D O I：

10.1016/0022-328X(90)85111-B

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The direction of optical induction is inverted in going from pyridineoxazoline 1 to picolineoxazoline 2 as cocatalyst in the Rh-catalyzed asymmetric hydrosilylation of acetophenone with diphenylsilane. In the case of ligand 2, a 1.2-fold excess of the ligand is sufficient to achieve the highest enantiomeric excess. © 1990.

引用

页码：C81 / C83

页数：3

共 12 条

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BRUNNER, H ;

OBERMANN, U .

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[2] ASYMMETRIC SYNTHESES .20. ENANTIOSELECTIVE HYDROSILYLATION OF KETONES WITH [RH(COD)CL]2 THIAZOLIDINE CATALYSTS [J].

BRUNNER, H ;

BECKER, R ;

RIEPL, G .

ORGANOMETALLICS, 1984, 3 (09) :1354-1359

[3] ASYMMETRIC HYDROSILYLATION OF ACETOPHENONE WITH RHODIUM-COMPLEXES OF OPTICALLY-ACTIVE SCHIFF-BASES [J].

BRUNNER, H ;

RIEPL, G .

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[4]

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[5]

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[8]

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[9]

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[10]

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