A HIGHLY DIASTEREOFACIAL INTRAMOLECULAR DIELS-ALDER REACTION OF ALPHA,BETA-UNSATURATED CARBENE COMPLEXES TO DECALINS

被引：19

作者：

MULLER, G ^{[1
]}

JAS, G ^{[1
]}

机构：

[1] TECH UNIV BERLIN,INST ORGAN CHEM,STR 17 JUNI 135,W-1000 BERLIN 12,GERMANY

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 31期

关键词：

CARBENE COMPLEXES; IMDA REACTION OF; DIASTEREOFACIAL SELECTIVITY OF; DECALINS;

D O I：

10.1016/S0040-4039(00)60098-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alpha,beta-unsaturated Fischer carbene complexes (1,7,9-triene type) bearing a chiral centre allylic to the dienophile react to yield trans-fused decalins with high diastereoselectivity via intramolecular Diels-Alder reaction.

引用

页码：4417 / 4420

页数：4

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