FORMATION OF CYCLOPENTANES FROM DELTA-ETHYLENE MALONATES BY CATALYSIS IN PALLADIUM(0) - STEREOCHEMISTRY AND MECHANISM

被引：42

作者：

BALME, G

BOUYSSI, D

FAURE, R

GORE, J

VANHEMELRYCK, B

机构：

[1] ATOCHEM,CRRA,F-69310 PIERRE BENITE,FRANCE

[2] UNIV LYON 1,CHIM ANALYT LAB 2,F-69622 VILLEURBANNE,FRANCE

来源：

TETRAHEDRON | 1992年 / 48卷 / 19期

关键词：

D O I：

10.1016/S0040-4020(01)88469-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The treatment of the enolate of a delta-ethylenic malonate with an unsaturated iodide in the presence of a Palladium(O) complex leads stereospecifically to a cyclopentane with the simultaneous formation in a trans fashion of the two carbon-carbon bonds. All the results authorize to conclude that this cyclisation occurs by nucleophilic attack of the enolate onto the double bond activated by the sigma-palladic unsaturated species.

引用

页码：3891 / 3902

页数：12

共 18 条

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