ELECTRICAL-CONDUCTIVITY OF ALUMINA-PILLARED ALPHA-TIN PHOSPHATE

被引:10
作者
CRIADO, C [1 ]
BARRADO, JRR [1 ]
MAIRELESTORRES, P [1 ]
OLIVERAPASTOR, P [1 ]
CASTELLON, ER [1 ]
JIMENEZLOPEZ, A [1 ]
机构
[1] UNIV MALAGA,DEPT QUIM INORGAN CRISTALOG & MINERAL,E-29071 MALAGA,SPAIN
关键词
D O I
10.1016/0167-2738(93)90346-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
ac conductivity of Al2O3-Pillared tin(IV) phosphate and the Li+ exchanged sample have been measured by an impedance method. The material Li+ exchanged pillared alpha-tin phosphate is dual, with two types of charge carriers, H+ from zeolite water and Li+. Conductivity is related to zeolitic water at low temperature, whereas at T> 250-degrees-C is due to Li+ ions. The conduction is reversible in the interval 250-500-degrees-C.
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页码:139 / 142
页数:4
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