ADDITION OF DIETHYL BROMODIFLUOROMETHYLPHOSPHONATE TO VARIOUS ALKENES INITIATED BY CO(III)/ZN BIMETAL REDOX SYSTEM

被引：36

作者：

HU, CM

CHEN, J

机构：

[1] Shanghai Institute of Organic Chemistry, Academia Sinica, Shanghai 200032

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 03期

关键词：

D O I：

10.1039/p19930000327

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The addition of diethyl bromodifluoromethylphosphonate 1 to various alkenes 2 initiated by cobaloxime(III)/Zn bimetal redox system gives 1:1 Michael-type adducts 3 in moderate to good yields. A radical mechanism is proposed.

引用

页码：327 / 330

页数：4

共 23 条

[1] SYNTHESIS AND CHARACTERIZATION OF A NEW FLUORINE SUBSTITUTED NONIONIC DINUCLEOSIDE PHOSPHONATE ANALOG, P-DEOXY-P-(DIFLUOROMETHYL)THYMIDYLYL (3'-]5') THYMIDINE
BERGSTROM, DE
SHUM, PW
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (17) : 3953 - 3958
[2] SYNTHESIS AND NMDA RECEPTOR-BINDING OF 2-AMINO-7,7-DIFLUORO-7-PHOSPHONOHEPTANOIC ACID
BIGGE, CF
DRUMMOND, JT
JOHNSON, G
[J]. TETRAHEDRON LETTERS, 1989, 30 (50) : 7013 - 7016
[3] THE SYNTHESIS OF ISOPRENOID (PHOSPHINYLMETHYL)PHOSPHONATES
BILLER, SA
FORSTER, C
[J]. TETRAHEDRON, 1990, 46 (19) : 6645 - 6658
[4] BLACKBURN GM, 1981, CHEM IND-LONDON, P134
[5] MICHAELIS-ARBUZOV PREPARATION OF HALO-F-METHYLPHOSPHONATES
BURTON, DJ
FLYNN, RM
[J]. JOURNAL OF FLUORINE CHEMISTRY, 1977, 10 (04) : 329 - 332
[6] DIFLUOROMETHYLENE EXCHANGE IN THE PREPARATION OF FLUORINATED BIS-PHOSPHONATES
BURTON, DJ
ISHIHARA, T
FLYNN, RM
[J]. JOURNAL OF FLUORINE CHEMISTRY, 1982, 20 (01) : 121 - 126
[7] SYNTHESIS OF (SULFODIFLUOROMETHYL)PHOSPHONIC ACID
BURTON, DJ
MODAK, AS
GUNERATNE, R
SU, DB
CEN, WB
KIRCHMEIER, RL
SHREEVE, JM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (05) : 1773 - 1776
[8] FLUORINATED ORGANOMETALLICS - PERFLUOROALKYL AND FUNCTIONALIZED PERFLUOROALKYL ORGANOMETALLIC REAGENTS IN ORGANIC-SYNTHESIS
BURTON, DJ
YANG, ZY
[J]. TETRAHEDRON, 1992, 48 (02) : 189 - 275
[9] SYNTHESIS OF A DIFLUOROMETHYLENEPHOSPHONATE ANALOG OF GLYCEROL-3-PHOSPHATE - A SUBSTRATE FOR NADH LINKED GLYCEROL-3-PHOSPHATE DEHYDROGENASE
CHAMBERS, RD
JAOUHARI, R
OHAGAN, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (17) : 1169 - 1170
[10] FLUORINE IN ENZYME CHEMISTRY .2. THE PREPARATION OF DIFLUOROMETHYLENEPHOSPHONATE ANALOGS OF GLYCOLYTIC PHOSPHATES - APPROACHING AN ISOSTERIC AND ISOELECTRONIC PHOSPHATE MIMIC
CHAMBERS, RD
JAOUHARI, R
OHAGAN, D
[J]. TETRAHEDRON, 1989, 45 (16) : 5101 - 5108

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