Potassium Superoxide and the Three-Electron Bond

被引：49

作者：

Neuman, Edward W. ^{[1
]}

机构：

[1] CALTECH, Pasadena, CA USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1934年 / 2卷 / 01期

关键词：

D O I：

10.1063/1.1749353

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The highest oxide of potassium is shown to be paramagnetic, with a susceptibility corresponding to the formula KO2, the crystals being supposed to contain O-2 ions in a (II)-I-2 state. The electronic structure : O O is proposed for the superoxide ion. It is suggested that the substance be called potassium superoxide rather than tetroxide.

引用

页数：3

共 6 条

[1] The three-electron bond in chlorine dioxide
Brockway, LO
[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1933, 19 : 303 - 307
[2] The electron diffraction investigation of the molecular structure of cyanogen and diacetylene (With a note on chlorine dioxide)
Brockway, LO
[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1933, 19 : 868 - 874
[3] Holt, 1894, J CHEM SOC T, P432
[4] Lewis G. N., 1923, VALENCE STRUCTURE AT, P80
[5] Pauling, 1931, J AM CHEM SOC, V53, P1367
[6] Pauling, 1931, J AM CHEM SOC, V53, P3225

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