NOVEL PALLADIUM(II)-CATALYZED CYCLIZATION OF AZIRIDINES AND SULFUR DIIMIDES

被引：25

作者：

BAEG, JO

ALPER, H

机构：

[1] Department of Chemistry, University of Ottawa, Ottawa, 10 Marie Curie, Ontario

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1994年 / 116卷 / 04期

关键词：

D O I：

10.1021/ja00083a007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis(benzonitrile)palladium dichloride is an effective catalyst for the cyclization reaction of aziridines and sulfur diimides, in toluene, affording imidazolidinathiones in 52-70% yield. Reaction of an aziridine, labeled with C-13 at one of the ring carbons, with a sulfur diimide resulted in incorporation of the label at the 2- and 5-positions of the imidazolidinethione. Thiazolidinimine formation results from the palladium(II)-catalyzed reaction of an aziridine with phenyl isothiocyanate.

引用

页码：1220 / 1224

页数：5

共 30 条

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