INTERPRETATION OF POLYAZULENE ELECTROPOLYMERIZATION CONSIDERING FARADAIC CURRENT EFFICIENCY AND CAPACITIVE CURRENT EFFECTS DURING THE GROWTH AND REDOX SWITCHING STEPS

被引：13

作者：

BRUCKENSTEIN, S

SHARKEY, JW

机构：

[1] State Univ of New York at Buffalo,, Buffalo, NY, USA, State Univ of New York at Buffalo, Buffalo, NY, USA

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1988年 / 241卷 / 1-2期

关键词：

CHEMICAL REACTIONS - Redox - ELECTROCHEMISTRY - HYDROGEN - Production - MONOMERS - Polymerization - ORGANIC COMPOUNDS - Oxidation;

D O I：

10.1016/0022-0728(88)85127-1

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A theoretical analysis of the electropolymerization of azulene at a rotating ring-disk electrode is presented. This analysis provides a method for determining the current efficiency of electropolymerization. The oxidation of azulene to polyazulene in acetonitrile as solvent is a convective-diffusion controlled process that proceeds with 100% current efficiency. A positively charged site is associated with at least two non-terminal monomer units in the oxidized form of the polymer. Hydrogen ion has been identified and quantitated as a product of the electropolymerization process. No hydrogen ions are produced by the redox process involving only the polymer film.

引用

页码：211 / 230

页数：20

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