ELECTRONIC AND STERIC SUBSTITUENT EFFECTS ON THE DEACTIVATION BEHAVIOR OF FULGIDES

被引：7

作者：

ILGE, HD

GOLDITZ, R

机构：

[1] Chemistry Department, Friedrich-Schiller-University

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1990年 / 218卷

关键词：

D O I：

10.1016/0022-2860(90)80241-B

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The photoisomerization about the α-β and γ-δ double bonds and the electrocyclic ring-closure reaction are competing processes in the excited singlet state of phenylfulgides and heterocyclic fulgides. Own experimental results and data given in the literature are interpreted in terms of π-bond orders and free-valence indices for the bond forming atoms in the S1 state calculated by a Pariser-Parr-Pople method. © 1990.

引用

页码：39 / 44

页数：6

共 24 条

[1] PHOTOCHEMICAL ISOMERIZATION IN THE ABSENCE OF A POTENTIAL BARRIER
AKESSON, E
BERGSTROM, H
SUNDSTROM, V
GILLBRO, T
[J]. CHEMICAL PHYSICS LETTERS, 1986, 126 (05) : 385 - 393
[2] PHOTOCHEMISTRY OF DI-PARA-CUMENYLFULGIDE (BIS-PARA-CUMENYLMETHYLENESUCCINIC ANHYDRIDE)
BERCOVICI, T
COHEN, MD
FISCHER, E
SINNREICH, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1977, (01): : 1 - 6
[3] COHEN MD, 1970, J CHEM SOC B, P1036
[4] PHOTOCHROMIC SYSTEMS .2. STUDIES ON THE PHOTOREACTIONS AND THE PHOTOPOLYCHROMIC PROPERTIES OF (E)-(2,5-DIMETHOXYPHENYL-SUBSTITUTED)METHYLENE ISOPROPYLIDENESUCCINIC ANHYDRIDES
CRESCENTE, O
HELLER, HG
PATHARAKORN, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1986, (09): : 1599 - 1602
[5] DEBLAUWE V, 1988, MAKROMOL CHEM, V189, P2503
[6] EMISSIONS OF STERICALLY HINDERED STILBENE DERIVATIVES AND RELATED COMPOUNDS .4. LARGE CONFORMATIONAL DIFFERENCES BETWEEN GROUND AND EXCITED-STATES OF STERICALLY HINDERED STILBENES - IMPLICATIONS REGARDING STOKES SHIFTS AND VISCOSITY OR TEMPERATURE-DEPENDENCE OF FLUORESCENCE YIELDS
FISCHER, G
SEGER, G
MUSZKAT, KA
FISCHER, E
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1975, (14): : 1569 - 1576
[7] TEMPERATURE DEPENDENCE OF PHOTOISOMERIZATION .6. VISCOSITY EFFECT
GEGIOU, D
MUSZKAT, KA
FISCHER, E
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (01) : 12 - &
[8] TEMPERATURE DEPENDENCE OF PHOTOISOMERIZATION .V. EFFECT OF SUBSTITUENTS ON PHOTOISOMERIZATION OF STILBENES AND AZOBENZENES
GEGIOU, D
MUSZKAT, KA
FISCHER, E
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (15) : 3907 - &
[9] PHOTOCHROMIC HETEROCYCLIC FULGIDES .4. THE THERMAL AND PHOTOCHEMICAL-REACTIONS OF "(E)-ISOPROPYLIDENE-[ALPHA-(2-THENYL AND -(3-THIENYL)ETHYLIDENE]SUCCINIC ANHYDRIDES AND RELATED-COMPOUNDS
GLAZE, AP
HARRIS, SA
HELLER, HG
JOHNCOCK, W
OLIVER, SN
STRYDOM, PJ
WHITTALL, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1985, (05): : 957 - 961
[10] GUSTAV K, 1979, Z CHEM, V19, P219

← 1 2 3 →