EQUILIBRIUM-CONSTANT FOR THE REACTION CLO+O-2 REVERSIBLE CLO.O-2

被引：6

作者：

DEMORE, WB

机构：

[1] Jet Propulsion Laboratory, California Institute of Technology

来源：

GEOPHYSICAL RESEARCH LETTERS | 1990年 / 17卷 / 13期

关键词：

D O I：

10.1029/GL017i013p02353

中图分类号：

P [天文学、地球科学];

学科分类号：

07 ;

摘要：

Photolysis of cl2/cl2o/o2 mixtures at 197 K has been used to place an upper limit of 4 X 10(-18) cm3 on the equilibrium constant for the c10 + o2 < -- > ClO.O2 reaction at the temperature. This value is three orders of magnitude below the current NASA recommendation [DeMore et al., 1990]. Estimating S(o) (ClO.O2) as 73 cal/mol-K, the bond energy for the complex is less than 7.7 kcal/mole.

引用

页码：2353 / 2355

页数：3

共 6 条

[1] ULTRAVIOLET-SPECTRUM AND CHEMICAL-REACTIVITY OF THE CLO DIMER [J].