THE REACTION OF PENTAFLUORONITROSOBENZENE WITH OS3(CO)12 - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [OS3(CO)9(MU-3-NC6F5)2]

被引：2

作者：

ANG, HG

KWIK, WL

ONG, KK

机构：

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1992年 / 56卷 / 01期

关键词：

D O I：

10.1016/S0022-1139(00)80179-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of pentafluoronitrosobenzene with Os3(CO)12 at 125-degrees-C in octane leads to the formation of a new bis(pentafluorophenylimido)triosmium cluster, [Os3(CO)9(mu-3-NC6F5)2] (I). Cluster I has been shown by X-ray crystallographic studies to consist of an open triosmium framework capped by triply bridging pentafluorophenylimido ligands.

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页码：45 / 49

页数：5

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