PREPARATION OF CHIRAL STRAIGHT-CHAIN COMPOUNDS WITH SYNDIOTACTIC METHYL FUNCTION

被引：7

作者：

MATSUKUMA, A ^{[1
]}

NAGUMO, S ^{[1
]}

SUEMUNE, H ^{[1
]}

SAKAI, K ^{[1
]}

机构：

[1] KYUSHU UNIV,FAC PHARMACEUT SCI,FUKUOKA 812,JAPAN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 51期

关键词：

3R; 5R-DIMETHYLCYCLOHEXANONE; CHIRAL STRAIGHT-CHAIN; INTERMOLECULAR ALDOL CONDENSATION; RING CLEAVAGE; 13-MEMBERED RING LACTONE; SYNDIOTACTIC;

D O I：

10.1016/0040-4039(91)80534-D

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(3R,5R)-Dimethylcyclohexanone was converted to chiral straight-chain compounds with syndiotactic methyl function via intermolecular aldol condensation followed by ring cleavage reaction.

引用

页码：7559 / 7562

页数：4

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