NEW C-N-C BOND FORMATION REACTION USING NITROGENATION-TRANSMETALATION PROCESS - NOVEL RING CONSTRUCTION OF INDOLE AND QUINOLINE DERIVATIVES

被引：19

作者：

MORI, M

UOZUMI, Y

SHIBASAKI, M

机构：

[1] HOKKAIDO UNIV,GRAD SCH PHARMACEUT SCI,SAPPORO,HOKKAIDO 060,JAPAN

[2] HOKKAIDO UNIV,CATALYT RES CTR,SAPPORO,HOKKAIDO 060,JAPAN

[3] UNIV TOKYO,FAC PHARMACEUT SCI,BUNKYO KU,TOKYO 113,JAPAN

来源：

HETEROCYCLES | 1992年 / 33卷 / 02期

关键词：

D O I：

10.3987/COM-91-S88

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ketones and aryl or vinyl halides couple to give divinyl- or arylvinylamines in the presence of the titanium-isocyanate complex [3 THF.Mg2Cl2O.TiNCO] (1) and a palladium catalyst, via transmetallation of the titano imine complex (3) with aryl- or vinylpalladium bromide.

引用

页码：819 / 830

页数：12

共 14 条

[1]

DILWORTH JR, 1982, COMPREHENSIVE ORGANO, V8, P1087

[2]

DUFOUR JC, 1989, TETRAHEDRON LETT, V34, P3429

[3]

GEORGE TA, 1983, HOMOGENEOUS CATALYSI, P405

[4] A NOVEL AND EFFICIENT SYNTHESIS OF THE ASPIDOSPERMA ALKALOID RING-SYSTEM - N(A)-BENZYLDEETHYLASPIDOSPERMIDINE [J].