THE SYNTHESIS AND REACTIONS WITH NEUTRAL MONODENTATE LIGANDS OF THE 7-COORDINATE COMPLEX [MOCL(GECL3)(CO)(3)(NCME)(2)]

被引：21

作者：

BAKER, PK

APKENDRICK, D

机构：

[1] Department of Chemistry, University of Wales, Bangor

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 466卷 / 1-2期

关键词：

MOLYBDENUM; ACETONITRILE; GERMANIUM; MONODENTATE;

D O I：

10.1016/0022-328X(94)88039-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of fac-[Mo(CO)(3)(NCMe)(3)] (prepared in situ) with an equimolar quantity of GeCl4 rapidly affords the molybdenum(II) seven-coordinate complex [MoCl(GeCl3)(CO)(3)(NCMe)(2)] (1) in quantitative yield. Equimolar quantities of 1 and L (L = PPh(3), AsPh(3) or SbPh(3)) react in CH2Cl2 or NCMe to give [MoCl(GeCl3)(CO)(3)(NCMe)L] or [MoCl(GeCl3)(CO)(2)(NCMe)(2)L], respectively. The reactions of [MoCl(GeCl3)(CO)(3)(NCMe)(PPh(3))] and [MoCl(GeCl3)(CO)(2)(NCMe)(2)(PPh(3))] with a series of neutral and anionic donor ligands are described. Complex 1 reacts with two equivalents of L (L = PPh(3), AsPh(3), SbPh(3) or PPh(2)Cy) in CH2Cl2 to afford [MoCl(GeCl3)(CO)(2)(NCMe)(PPh(3))(2)] and [MoCl(GeCl3)(CO)(3)L(2)]. Reactions of [MoCl(GeCl3)(CO)(2)(NCMe)(PPh(3))(2)] are also discussed.

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页码：139 / 146

页数：8

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