Collisional quenching in the photochemical isomerisation of 1,3.5-cycloheptatriene

被引:7
作者
Atkinson, R. [1 ]
Thrush, B. A. [1 ]
机构
[1] Univ Cambridge, Dept Phys Chem, Cambridge CB2 1TN, England
关键词
D O I
10.1016/0009-2614(69)87009-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The photochemical isomerisation of 1,3,5-cycloheptatriene to toluene occurs via the vibrationally excited ground state molecule. Studies of this isomerisation at seven wavelengths and its quenching by various added gases yield values for the vibrational energy removed per collision.
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页码:684 / 686
页数:3
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