THE TETRAVALENCE OF C28

被引：30

作者：

FOWLER, PW

AUSTIN, SJ

SANDALL, JPB

机构：

[1] Department of Chemistry, University of Exeter, Exeter

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1993年 / 05期

关键词：

D O I：

10.1039/p29930000795

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The tetravalence of tetrahedral C28 and the stabilities of the hypothetical species C28(4+), C28H4 and U @ C28 are all rationalised by a simple Huckel molecular orbital treatment that also predicts stability for C24N4.

引用

页码：795 / 797

页数：3

共 6 条

[1] 3 CANDIDATES FOR THE STRUCTURE OF C-84 [J].

FOWLER, PW .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1991, 87 (12) :1945-1946

[2] URANIUM STABILIZATION OF C28 - A TETRAVALENT FULLERENE [J].

GUO, T ;

DIENER, MD ;

CHAI, Y ;

ALFORD, MJ ;

HAUFLER, RE ;

MCCLURE, SM ;

OHNO, T ;

WEAVER, JH ;

SCUSERIA, GE ;

SMALLEY, RE .

SCIENCE, 1992, 257 (5077) :1661-1664

[3] ARE ENDOHEDRAL METAL (IV)C28 COMPOUNDS HYPERVALENT [J].

HABERLEN, OD ;

ROSCH, N ;

DUNLAP, BI .

CHEMICAL PHYSICS LETTERS, 1992, 200 (04) :418-423

[4] THE STABILITY OF THE FULLERENES C-24, C-28, C-32, C-36, C-50, C-60 AND C-70 [J].

KROTO, HW .

NATURE, 1987, 329 (6139) :529-531

[5]

KROTO HW, IN PRESS J ORGANOMET

[6] SUBSTITUTIONAL SYMMETRIES AND EXTRA DEGENERACIES OF REAL SYMMETRIC-MATRICES [J].

SIDDALL, TH ;

SULLIVAN, JJ .

JOURNAL OF MATHEMATICAL PHYSICS, 1988, 29 (05) :1091-1096

← 1 →