DEPENDENCE OF MOLAR HEAT-CAPACITY OF LIQUID ALKANOLS C-3-C-5 ON THEIR STRUCTURE

被引：6

作者：

BURES, M

ZABRANSKY, M

SVOBODA, V

机构：

[1] Department of Physical Chemistry, Institute of Chemical Technology

来源：

THERMOCHIMICA ACTA | 1994年 / 245卷

关键词：

ALCOHOL; ALKANOL; GAS; HYDROGEN BOND; ISOMER; LIQUID; MOLAR HEAT CAPACITY;

D O I：

10.1016/0040-6031(94)85074-7

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The dependence of molar heat capacities upon the molecular structure of isomeric alcohols C-3-C-5 is discussed in the liquid and ideal gas states. In general, the differences of the heat capacities for the ideal gas state are small in comparison to those for the liquid state. The larger differences for the liquid state are due to steric effects which occur during the formation of hydrogen bonds between molecules.

引用

页码：145 / 153

页数：9

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