ARTIFICIAL RECEPTORS FOR CARBOHYDRATE-DERIVATIVES

被引：110

作者：

BONARLAW, RP ^{[1
]}

DAVIS, AP ^{[1
]}

MURRAY, BA ^{[1
]}

机构：

[1] UNIV DUBLIN TRINITY COLL,DEPT CHEM,DUBLIN 2,IRELAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 12期

关键词：

D O I：

10.1002/anie.199014071

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Clear evidence of encapsulation of pyranosides in the macrocycle 1 (R = H. R' = Bn) was afforded by NMR and IR spectroscopic investigations of the reaction of 1 with 2 in CDCI 3 and force field calculations for the methyl analogue of 2. The macrocycle is thus one of the first synthetic carbohydrate receptors. Its cavity is large enough to fix the guest molecule from all sides by oriented hydrogen bonds.

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页码：1407 / 1408

页数：2

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