DIRECTED REGIOCHEMICAL CONTROL IN THE RING EXPANSION REACTIONS OF A SUBSTITUTED TRANS-DECALONE

被引：16

作者：

AUBE, J

HAMMOND, M

机构：

[1] Department of Medicinal Chemistry, The University of Kansas, Lawrence

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 21期

关键词：

D O I：

10.1016/S0040-4039(00)88999-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A derivative of the Wieland-Miescher ketone can selectively be converted into either regioisomeric ring-expanded lactam. The synthesis of the diastereomeric N-α-methylbenzyl oxaziridine derivatives determines the regiochemistry of the product lactam and additionally allows the separation of a racemic substrate into regio- and enantioisomeric lactams. © 1990.

引用

页码：2963 / 2966

页数：4

共 20 条

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