FLOCCULATION OF OXIDES USING POLYETHYLENE OXIDE

被引:52
作者
KOKSAL, E [1 ]
RAMACHANDRAN, R [1 ]
SOMASUNDARAN, P [1 ]
MALTESH, C [1 ]
机构
[1] COLUMBIA UNIV,HENRY KRUMB SCH MINES,LANGMUIR CTR COLLOIDS & INTERFACES,NEW YORK,NY 10027
基金
美国国家科学基金会;
关键词
D O I
10.1016/0032-5910(90)80112-C
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Flocculation of oxides using polyethylene oxide was investigated. Polyethylene oxide adsorbed strongly on and flocculated sodium kaolinite. H-bonding is considered to be the driving force for polyethylene oxide adsorption on kaolinite. The mechanism of adsorption of polyethylene oxide on kaolinite was examined by studying the adsorption/flocculation characteristics of different oxide minerals using the same polymer. Polyethylene oxide flocculated silica gel but did not adsorb on or flocculate hematite and alumina. Quartz was flocculated only below pH 3. Results are examined in terms of the type of surface groups and the degree of hydration of the solids. It is proposed that adsorption of polyethylene oxide on solids requires some optimum hydroxylation of the surface with displaceable water species. © 1990.
引用
收藏
页码:253 / 259
页数:7
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