EFFECTS OF SOLVENT ON THE ELECTRONIC ABSORPTION AND FLUORESCENCE-SPECTRA OF QUINAZOLINES, AND DETERMINATION OF THEIR GROUND AND EXCITED SINGLET-STATE DIPOLE-MOMENTS

被引：45

作者：

AARON, JJ ^{[1
]}

TINE, A ^{[1
]}

GAYE, MD ^{[1
]}

PARKANYI, C ^{[1
]}

BONIFACE, C ^{[1
]}

BIEZE, TWN ^{[1
]}

机构：

[1] FLORIDA ATLANTIC UNIV,DEPT CHEM,BOCA RATON,FL 33431

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1991年 / 47卷 / 3-4期

关键词：

D O I：

10.1016/0584-8539(91)80119-4

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The electronic absorption, and fluorescence excitation and emission spectra of 11 quinazolines have been measured at room temperature (298 K) in several solvents of different polarities (cyclohexane, dioxane, ethylether, chloroform, ethylacetate, 1-butanol, 2-propanol, ethanol, methanol, acetonitrile, dimethylformamide and dimethyl sulfoxide). The effects of the solvent upon the spectral properties are discussed. Experimental ground-state dipole moments were measured for quinazolines and were used in combination with the spectral results to evaluate their first excited singlet-state dipole moments by means of the solvatochromic shift method. The theoretical ground and excited singlet-state dipole moments for selected quinazolines were calculated as a vector sum of the pi-component (obtained by the PPP method) and the sigma-component (obtained from sigma-bond moments). A reasonable agreement was observed between the experimental and the theoretical values. Excited singlet-state dipole moments are higher than the ground-state values for most quinazolines.

引用

页码：419 / 430

页数：12

共 26 条

[1] EXPERIMENTAL AND THEORETICAL DIPOLE-MOMENTS OF PURINES IN THEIR GROUND AND LOWEST EXCITED SINGLET-STATES [J].