ALUMINUM-FUSED BIS-PARA-TERT-BUTYLCALIX[4]ARENE - A DOUBLE CONE WITH 2 PI-ARENE...H INTERACTIONS FOR INCLUDED METHYLENE-CHLORIDE

被引：109

作者：

ATWOOD, JL ^{[1
]}

BOTT, SG ^{[1
]}

JONES, C ^{[1
]}

RASTON, CL ^{[1
]}

机构：

[1] GRIFFITH UNIV,DIV SCI & TECHNOL,NATHAN,QLD 4111,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 18期

关键词：

D O I：

10.1039/c39920001349

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of p-tert-butylcalix[4]arene 1 with [H3Al(NMe3)]2 results in trimetallation and deprotonation by the tertiary amine, yielding the bis(calix[4]arene), [{(1 - H4)Al}2]2- [HNMe3]+2, 2, which has been isolated with included methylene chloride; distorted five-coordinate O-bound aluminium centres [Al-O 1.74(1)-2.35(1) angstrom] fuse the slightly flattened cone calixarene units with the methylene chloride H-atoms residing over two opposite aromatic rings in each cone, C...ring centroid 3.54 angstrom.

引用

页码：1349 / 1351

页数：3

共 26 条

[1] TERTIARY AMINE STABILIZED DIALANE
ATWOOD, JL
BENNETT, FR
ELMS, FM
JONES, C
RASTON, CL
ROBINSON, KD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (21) : 8183 - 8185
[2] ATWOOD JL, 1991, NATURE, V349, P684
[3] MONO-METALLOCENE AND BIS-METALLOCENE CALIX[4]ARENE HYDROPHOBIC RECEPTOR MOLECULES - THEIR SYNTHESIS, STRUCTURE AND ELECTROCHEMICAL PROPERTIES
BEER, PD
KEEFE, AD
DREW, MGB
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 378 (03) : 437 - 447
[4] BIS-FERROCENE DERIVATIVES OF BRIDGED CALIX[4]ARENES - SYNTHESIS, X-RAY CRYSTAL-STRUCTURE AND ELECTROCHEMICAL PROPERTIES
BEER, PD
KEEFE, AD
BOHMER, V
GOLDMANN, H
VOGT, W
LECOCQ, S
PERRIN, M
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 421 (2-3) : 265 - 273
[5] ALTERNATIVE METHODS OF MODIFYING THE CALIXARENE CONFORMATION - THE SYNTHESIS AND MOLECULAR-STRUCTURES OF TERT-BUTYLCALIX[4]ARENE METHYL-ETHER COMPLEXED WITH ALUMINUM ALKYL SPECIES
BOTT, SG
COLEMAN, AW
ATWOOD, JL
[J]. JOURNAL OF INCLUSION PHENOMENA, 1987, 5 (06): : 747 - 758
[6] INCLUSION OF BOTH CATION AND NEUTRAL MOLECULE BY A CALIXARENE - STRUCTURE OF THE [PARA-TERT-BUTYLMETHOXYCALIX[4]ARENE-SODIUM-TOLUENE]+CATION
BOTT, SG
COLEMAN, AW
ATWOOD, JL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (07) : 1709 - 1710
[7] BOTT SG, 1986, THESIS U ALABAMA
[8] CORRAZZA F, 1990, J CHEM SOC CHEM COMM, P640
[9] CORRAZZA F, 1990, J CHEM SOC CHEM COMM, P1083
[10] FURPHY BM, 1989, J CHEM SOC DA, P217

← 1 2 3 →