PREPARATION AND CHARACTERIZATION OF T-CAGE-TYPE S-BRIDGED RH(III)CD(II) POLYNUCLEAR COMPLEXES WITH 2-AMINOETHANETHIOLATE

被引：28

作者：

KONNO, T

KAGEYAMA, Y

OKAMOTO, K

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 07期

关键词：

D O I：

10.1246/bcsj.67.1957

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of fac(S)-[Rh(aet)3] with Cd-NO3)2 in water gave a T-cage-type S-bridged Rh(III)4Cd(II)3 complex with a ''defective'' [Cd3HO]5+ core, [{Rh(aet)3}4Cd3HO](NO3)5 (1). The corresponding T-cage-type Rh(III)4Cd(II)4 complex with a ''complete'' [Cd4O]6+ core, [{Rh(aet)3}Cd4O](NO3)6 (2), was formed by the reaction of fac(S)-[Rh(aet)3] With a mixture of Cd(NO3)2 and CdO in water. These complexes were characterized by a combination of X-ray diffraction and spectroscopic methods.

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页码：1957 / 1960

页数：4

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