REDUCTION OF THEBAINE WITH MIXED HYDRIDE REDUCING AGENTS

被引：7

作者：

BENTLEY, KW

LEWIS, JW

TAYLOR, JB

机构：

[1] Reckitt and Sons Ltd., Research Laboratories

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 15期

关键词：

D O I：

10.1039/j39690001945

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reduction of thebaine with lithium aluminium hydride-aluminium chloride mixtures gives either thebainone-A enol methyl ether or neodihydrothebaine as the major product, depending on the ratio used. A novel product, isometathebainone enol methyl ether, has been isolated from the reduction with aluminium hydride, and its structure has been confirmed by conversion into dihydrometathebainone.

引用

页码：1945 / &

共 9 条

[1] COMPOSITION OF MIXED HYDRIDE REAGENTS . A STUDY OF SCHLESINGER REACTION [J].