THERMAL AND PHOTOCHEMICAL-REACTIONS OF RHODIUM(TRIALKYLSILYL)HYDRIDE COMPLEXES - NMR AND BONDING OF POLY(SILYL)(HYDRIDE) COMPLEXES

被引：44

作者：

DUCKETT, SB ^{[1
]}

PERUTZ, RN ^{[1
]}

机构：

[1] UNIV YORK,DEPT CHEM,YORK YO1 5DD,N YORKSHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 01期

关键词：

D O I：

10.1039/c39910000028

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thermal reaction of (eta-5-C5H5)Rh(C2H4)(SiR3) with R'3SiH (R,R' = Et, Me) generates the sterically hindered poly(silyl) complexes (eta-5-C5H5)Rh(SiR'3)2(SiR3)H, some of which contain an eta-2-silane ligand; these complexes undergo silyl migrations with an excess of silane and also prove photosensitive.

引用

页码：28 / 31

页数：4

共 23 条

[1] PHOTOCHEMICAL SUBSTITUTION OF ETHENE AND H/D EXCHANGE IN (ETA-5-CYCLOPENTADIENYL)BIS(ETHENE)RHODIUM
BELT, ST
DUCKETT, SB
HADDLETON, DM
PERUTZ, RN
[J]. ORGANOMETALLICS, 1989, 8 (03) : 748 - 759
[2] BROOKHART M, 1988, J AM CHEM SOC, V10, P8719
[3] SYNTHESIS AND 2D-(H-1,RH-103)-NMR STUDY OF THE 1ST NONCLASSICAL POLYHYDRIDO COMPLEX STABILIZED BY A NITROGEN DONOR LIGAND
BUCHER, UE
LENGWEILER, T
NANZ, D
VONPHILIPSBORN, W
VENANZI, LM
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (05): : 548 - 549
[4] ELECTRONIC STABILITY OF METAL DIHYDROGEN AND METAL-POLYHYDROGEN COMPLEXES
BURDETT, JK
PHILLIPS, JR
POURIAN, MR
POLIAKOFF, M
TURNER, JJ
UPMACIS, R
[J]. INORGANIC CHEMISTRY, 1987, 26 (18) : 3054 - 3063
[5] KINETICS AND MECHANISM OF THE INSERTION OF OLEFINS INTO NIOBIUM-HYDRIDE AND TANTALUM-HYDRIDE BONDS - A STUDY OF THE COMPETITION BETWEEN STERIC AND ELECTRONIC EFFECTS
BURGER, BJ
SANTARSIERO, BD
TRIMMER, MS
BERCAW, JE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (10) : 3134 - 3146
[6] ORGANOMETALLOIDAL DERIVATIVES OF THE TRANSITION-METALS .19. BASE-INDUCED MIGRATIONS OF GERMYL, STANNYL, AND PLUMBYL GROUPS TO THE CYCLOPENTADIENYL LIGAND IN THE SYSTEM (ETA-5-C5H5)M(CO)NER3 (M=FE, MO, W - N=2, 3 - E=GE, SN, PB - R=ME, PH)
CERVANTES, J
VINCENTI, SP
KAPOOR, RN
PANNELL, KH
[J]. ORGANOMETALLICS, 1989, 8 (03) : 744 - 748
[7] PHOTOCHEMICAL OXIDATIVE ADDITION-REACTIONS OF (ETA-5-CYCLOPENTADIENYL)BIS(ETHENE)RHODIUM WITH DIHYDROGEN AND TRIALKYLSILANES - FORMATION AND ISOLATION OF RHODIUM(III) AND RHODIUM(V) HYDRIDES
DUCKETT, SB
HADDLETON, DM
JACKSON, SA
PERUTZ, RN
POLIAKOFF, M
UPMACIS, RK
[J]. ORGANOMETALLICS, 1988, 7 (07) : 1526 - 1532
[8] BIS(TRIETHYLSILYL)DIHYDRO(PENTAMETHYLCYCLOPENTADIENYL)RHODIUM - AN ORGANO-RHODIUM(V) COMPLEX
FERNANDEZ, MJ
MAITLIS, PM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (05) : 310 - 311
[9] SYNTHESIS, X-RAY, AND LOW-TEMPERATURE NEUTRON-DIFFRACTION STUDY OF A RHODIUM(V) COMPLEX - DIHYDRIDOBIS(TRIETHYLSILYL)-PENTAMETHYLCYCLOPENTADIENYLRHODIUM
FERNANDEZ, MJ
BAILEY, PM
BENTZ, PO
RICCI, JS
KOETZLE, TF
MAITLIS, PM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (19) : 5458 - 5463
[10] (PENTAMETHYLCYCLOPENTADIENYL)IRIDIUM POLYHYDRIDE COMPLEXES - SYNTHESIS OF INTERMEDIATES IN THE MECHANISM OF FORMATION OF (C5(CH3)5)IRH4 AND THE PREPARATION OF SEVERAL IRIDIUM(V) COMPOUNDS
GILBERT, TM
HOLLANDER, FJ
BERGMAN, RG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (12) : 3508 - 3516

← 1 2 3 →