PERTURBATIONS IN THE INFRARED-SPECTRUM OF MONOFLUOROACETYLENE, AND THEIR RELATIONSHIP TO INTRAMOLECULAR VIBRATIONAL-ENERGY REDISTRIBUTION

被引：25

作者：

HOLLAND, JK ^{[1
]}

LAWRANCE, WD ^{[1
]}

MILLS, IM ^{[1
]}

机构：

[1] FLINDERS UNIV S AUSTR,SCH PHYS SCI,ADELAIDE,SA 5001,AUSTRALIA

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1992年 / 151卷 / 02期

关键词：

D O I：

10.1016/0022-2852(92)90572-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Several high-order vibration-rotation perturbations in the high-resolution infrared spectrum of monofluoroacetylene, HCCF, are assigned and analyzed in detail. They result in avoided crossings in the rotational structure of several bands, and precise values for the effective high-order terms in the Hamiltonian have been determined. The significance of these results for intramolecular vibrational redistribution is discussed. © 1992.

引用

页码：369 / 377

页数：9

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