CHEMISTRY OF ORGANOMETALLIC METALLACYCLIC SUBGROUP METAL-COMPOUNDS .4. SYNTHESIS OF LI2NI-(CH2CH2CH2CH2)2(ET2O) AND ITS CONVERSION WITH CARBON-MONOXIDE TO LI2NI6(CO)12(THF)6

被引：11

作者：

FROHLICH, HO

HIPLER, B

HOFMANN, B

机构：

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 430卷 / 02期

关键词：

D O I：

10.1016/0022-328X(92)86001-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

LiCH2CH2CH2CH2Li reacts with Ni(C5H5)2 in Et2O to give Li2 activated Ni-(CH2CH2CH2CH2)2(Et2O) (1). The Ni(II) complex is remarkably resistant to beta-elimination. DTA investigations showed that thermal decomposition takes place at 105-degrees-C. Interaction of 1 with carbon monoxide yields red-colored Li2Ni6(CO)12(thf)6 (4). IR studies showed that the CO reaction is very rapid even at -78-degrees-C.

引用

页码：133 / 138

页数：6

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