SPINODAL DECOMPOSITION OF A 3-COMPONENT WATER-IN-OIL MICROEMULSION SYSTEM

被引:25
作者
MALLAMACE, F
MICALI, N
TRUSSO, S
CHEN, SH
机构
[1] CNR,INST SPECT TECHN,I-98166 MESSINA,ITALY
[2] MIT,DEPT NUCL ENGN,CAMBRIDGE,MA 02139
来源
PHYSICAL REVIEW E | 1995年 / 51卷 / 06期
关键词
D O I
10.1103/PhysRevE.51.5818
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We have performed a series of spinodal decomposition measurements of a three-component microemulsion system made of a surfactant Aerosol OT, water, and decane. The measurements were made by a temperature jump from a one-phase droplet microemulsion to a two-phase droplet microemulsion along the critical isovolume fraction line (10%) using a time resolved light scattering intensity measurement technique. All three stages of the evolution were studied. Time evolution of intensities for the initial stage follows closely the linearized theory. On the other hand, time evolution of the characteristic wave vector, the maximum scattering intensity, and the intensity distributions in the intermediate and late stages are in good agreement with recent dynamic scaling theories. © 1995 The American Physical Society.
引用
收藏
页码:5818 / 5823
页数:6
相关论文
共 22 条
[1]  
BINDER K, 1990, MATERIALS SCI TECHNO, V5, P405
[2]   FREE ENERGY OF A NONUNIFORM SYSTEM .1. INTERFACIAL FREE ENERGY [J].
CAHN, JW ;
HILLIARD, JE .
JOURNAL OF CHEMICAL PHYSICS, 1958, 28 (02) :258-267
[3]   THEORY AND EXPERIMENT OF ELECTRICAL-CONDUCTIVITY AND PERCOLATION LOCUS IN WATER-IN-OIL MICROEMULSIONS [J].
CAMETTI, C ;
CODASTEFANO, P ;
TARTAGLIA, P ;
ROUCH, J ;
CHEN, SH .
PHYSICAL REVIEW LETTERS, 1990, 64 (12) :1461-1464
[4]  
Chen SH, 1993, PROG COLL POL SCI S, V93, P311
[5]   A DYNAMIC SCALING ASSUMPTION FOR PHASE-SEPARATION [J].
FURUKAWA, H .
ADVANCES IN PHYSICS, 1985, 34 (06) :703-750
[6]   PINNING IN PHASE-SEPARATING SYSTEMS [J].
GLOTZER, SC ;
GYURE, MF ;
SCIORTINO, F ;
CONIGLIO, A ;
STANLEY, HE .
PHYSICAL REVIEW E, 1994, 49 (01) :247-258
[7]  
GOLDBURG WI, 1981, SCATTERING TECHNIQUE
[8]   LATE-STAGE DYNAMICS OF PHASE-SEPARATION PROCESSES OF BINARY-MIXTURES CONTAINING SURFACTANTS [J].
KAWAKATSU, T ;
KAWASAKI, K ;
FURUSAKA, M ;
OKABAYASHI, H ;
KANAYA, T .
JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (10) :8200-8217
[9]   KINETIC EQUATIONS AND TIME CORRELATION FUNCTIONS OF CRITICAL FLUCTUATIONS [J].
KAWASAKI, K .
ANNALS OF PHYSICS, 1970, 61 (01) :1-&
[10]  
KOGA T, 1991, PHYS REV A, V44, P817