ADDITION OF ALUMINUM-HYDRIDE TO FORMALDEHYDE

被引：16

作者：

COXON, JM ^{[1
]}

LUIBRAND, RT ^{[1
]}

机构：

[1] CALIF STATE UNIV HAYWARD,DEPT CHEM,HAYWARD,CA 94542

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 44期

关键词：

D O I：

10.1016/S0040-4039(00)61607-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Semiempirical and ab initio calculations show that aluminium hydride addition to formaldehyde occurs by formation of a complex which rearranges via a four-centre transition state to form an aluminium methoxide product.

引用

页码：7093 / 7096

页数：4

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