STEP-SCAN FOURIER-TRANSFORM INFRARED STUDY ON THE EFFECT OF DYNAMIC STRAIN ON ISOTACTIC POLYPROPYLENE

被引:51
作者
BUDEVSKA, BO
MANNING, CJ
GRIFFITHS, PR
ROGINSKI, RT
机构
[1] UNIV IDAHO,DEPT CHEM,MOSCOW,ID 83843
[2] AMOCO CORP,NAPERVILLE,IL 60566
关键词
STEP-SCAN FT-IR SPECTROMETRY; DYNAMIC RHEOOPTICAL SPECTRA; ISOTACTIC POLYPROPYLENE;
D O I
10.1366/0003702934065920
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Dynamic rheo-optical spectra of two isotactic polypropylene samples of different states of order were measured by step-scan FT-IR spectrometry. Experimental details and data collection considerations are discussed. The features in the dynamic spectra are found to be due to small wave-number shifts and absorption changes. The dynamic rheo-optical spectra depend strongly on the pretreatment of the samples, as well as on the polarization state of the infrared radiation used for analysis.
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页码:1843 / 1851
页数:9
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