SELECTIVE FORMATION OF PROPYNE BY PROTONATION OF AN ALLYL COMPLEX

被引：13

作者：

OGLIEVE, KE ^{[1
]}

HENDERSON, RA ^{[1
]}

机构：

[1] UNIV SUSSEX,AFRC,INST PLANT SCI RES,NITROGEN FIXAT LAB,BRIGHTON BN1 9RQ,E SUSSEX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 05期

关键词：

D O I：

10.1039/c39930000474

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of [MoH(eta3-C3H5)(Ph2PCH2CH2PPh2)2] with a large excess of anhydrous HCI in tetrahydrofuran rapidly yields [MoH2Cl2(Ph2PCH2CH2PPh2)2] and propyne, at lower concentrations of acid, propene is formed; the mechanism of these reactions has been established by detailed kinetic studies and product analyses.

引用

页码：474 / 476

页数：3

共 7 条

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