SYNTHESIS, STRUCTURE, AND REACTIVITY OF A ZIRCONOCENE COMPLEX OF CYCLOBUTENE

被引：54

作者：

FISHER, RA ^{[1
]}

BUCHWALD, SL ^{[1
]}

机构：

[1] MIT, DEPT CHEM, CAMBRIDGE, MA 02139 USA

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 03期

关键词：

D O I：

10.1021/om00117a057

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first structurally characterized transitionmetal complex of cyclobutene is described. The complex is formed by the elimination of methane from cyclobutylmethylzirconocene with subsequent trapping by trimethylphosphine. The reactivity of the complex with unsaturated organic molecules and its X-ray crystal structure are reported. © 1990, American Chemical Society. All rights reserved.

引用

页码：871 / 873

页数：3

共 41 条

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