ACTIVITY AND THERMORESISTANCE OF FUSED IRON CATALYSTS FOR AMMONIA-SYNTHESIS

被引:14
作者
KOWALCZYK, Z
JODZIS, S
机构
[1] Department of Chemistry, Warsaw University of Technology, PL-00-664 Warsaw
来源
APPLIED CATALYSIS | 1990年 / 58卷 / 01期
关键词
D O I
10.1016/S0166-9834(00)82276-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The activity and thermoresistance of five industrial catalysts were examined. Kinetic measurements were carried out in an isothermal, flow differential reactor under 10.0 MPa in the 400-520°C temperature range. In thermoresistance tests, overheating of the catalysts was carried out at 650°C for 24 h, or at 620°C for 24 to 192 h. The relationships obtained during both experimental tests were similar, with 24-h operating at 650°C giving a similar activity decrease as ageing for 192 h at 620°C. The chemical composition of the catalysts (XRF) was determined. © 1990.
引用
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页码:29 / 34
页数:6
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