ON THE GENERATION OF POLYCARBON NITRIDE RADICALS CNN. (N = 2-5) BY NEUTRALIZATION-REIONIZATION MASS-SPECTROMETRY

被引：27

作者：

SULZLE, D

SEEMAYER, K

WITULSKI, B

HOPF, H

SCHWARZ, H

机构：

[1] TECH UNIV BERLIN,INST ORGAN CHEM,STR 17,JUNI 135,W-1000 BERLIN 12,GERMANY

[2] TECH UNIV BRAUNSCHWEIG,INST ORGAN CHEM,W-3300 BRAUNSCHWEIG,GERMANY

来源：

CHEMISCHE BERICHTE | 1991年 / 124卷 / 06期

关键词：

INTERSTELLAR CHEMISTRY; POLYCARBON NITRIDE RADICALS; NEUTRALIZATION-REIONIZATION MASS SPECTROMETRY; TANDEM MASS SPECTROMETRY;

D O I：

10.1002/cber.19911240625

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title radicals, thought to be of prime importance in the genesis of interstellar organic molecules, are accessible in the gas phase by neutralization of the corresponding C(n)N+ ions (n = 2-5) using tandem mass spectrometry methods (neutralization-reionization mass spectrometry). Collision-induced dissociation reactions of mass-selected C(n)N+ are in keeping with the connectivity of a "carbon rod" bearing a nitrogen atom at one terminus.

引用

页码：1481 / 1483

页数：3

共 72 条

[1] SELECTED-ION FLOW TUBE STUDIES OF REACTIONS OF THE CARBENE CATION - C4N+ AND THEIR IMPLICATIONS FOR INTERSTELLAR GAS CLOUD CHEMISTRY [J].