TRICHLOROMETHOXYTIN(IV) DIMETHANOLATE, SNCL3(OCH3).2CH3OH

被引：5

作者：

REUTER, H

SCHRODER, D

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷

关键词：

D O I：

10.1107/S0108270191013288

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

M(r) = 320.19, triclinic, P1BAR, a = 7.552 (2), b = 8.114 (2), c = 9.714 (4) angstrom, alpha = 93.88 (2), beta = 102.04 (3), gamma = 114.80 (2)-degrees, V = 520.3 (4) angstrom 3, Z = 2, D(x) = 2.045 g cm-3, lambda(Mo K-alpha) = 0.71073 angstrom, mu = 29.57 cm-1, F(000) = 308, T = 210 (2) K, R = 0.056 for 2651 reflections with F(o) greater-than-or-equal-to 4-sigma(F(o)). The structure consists of dimeric SnCl3(OCH3).2CH3OH molecules possessing crystallographic 1BAR symmetry. The Sn atoms are octahedrally coordinated and bridged by two mu(2)-OCH3 groups. The two additional methanol molecules in the unit cell which complete the crystal structure are bonded via hydrogen bonds to the two solvent molecules coordinated to the Sn atoms.

引用

页码：1112 / 1114

页数：3

共 12 条

[1]

[Anonymous], 1986, SHELXS86 PROGRAM SOL

[2] CRYSTAL-STRUCTURES OF DI-MU-HYDROXO-BIS[AQUATRICHLOROTIN(IV)]-1,4-DIOXAN (1/3), DI-MU-HYDROXO-BIS[AQUATRICHLOROTIN(IV)]-1,8-EPOXY-PARA-MENTHANE (1/4), DI-MU-HYDROXO-BIS[AQUATRIBROMOTIN(IV)]-1,8-EPOXY-PARA-METHANE (1/4), DI-MU-HYDROXO-BIS[AQUATRICHLOROTIN(IV)]-WATER (1/4), AND CIS-DIA-QUATETRACHLOROTIN(IV)-WATER(1/3) [J].