DILITHIUM ACEPENTALENEDIIDE - AN UNUSUAL DIMER OF CONTACT ION TRIPLETS WITH BOWL-SHAPED DIANIONS

被引：32

作者：

HAAG, R

FLEISCHER, R

STALKE, D

DEMEIJERE, A

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,D-37077 GOTTINGEN,GERMANY

[2] UNIV GOTTINGEN,INST ORGAN CHEM,D-37077 GOTTINGEN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 13-14期

关键词：

ACEPENTALENES; FULLERENES; PENTALENES; STRUCTURE ELUCIDATION;

D O I：

10.1002/anie.199514921

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pure 4,7‐bis(trimethylstannyl)dihydroacepentalene 1 can be transformed cleanly into dilithium acepentalenediide 2 by treatment with methyllithium. In the crystal 2 adopts an interesting dimeric structure in which the convex sides of the two bowl‐shaped dianionic fragments face each other. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1492 / 1495

页数：4

共 93 条

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