A NOVEL TYPE OF PHOTOSUBSTITUTION OF [FAC-RE(BPY)(CO)3BR] (BPY = 2,2'-BIPYRIDINE) WITH P(OR)3 IN THE PRESENCE OF TRIETHYLAMINE - EFFICIENT FORMATION OF [RE(BPY)(CO)2[P(OR)3]2]+BR-

被引:12
作者
PAC, CJ
KASEDA, S
ISHII, K
YANAGIDA, S
机构
关键词
D O I
10.1039/c39910000787
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Photochemical ligand substitution of [fac-Re(bpy)(CO)3Br] with P(OEt)3 in the presence of triethylamine quantitatively gave [Re(bpy)(CO)2{P(OEt)3}3]+Br- without the intervention of a mono-substituted product.
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页码:787 / 788
页数:2
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共 11 条
[1]   A NEW PROCESS FOR SENSITIZATION OF KETONE PHOTO-REDUCTION - EXPLOITATION OF LOW-LYING METAL-TO-KETONE CHARGE-TRANSFER EXCITED-STATES [J].
FREDERICKS, SM ;
WRIGHTON, MS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (19) :6166-6168
[2]   PHOTOCHEMICAL AND ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE TO CARBON-MONOXIDE MEDIATED BY (2,2'-BIPYRIDINE)TRICARBONYLCHLORORHENIUM(I) AND RELATED COMPLEXES AS HOMOGENEOUS CATALYSTS [J].
HAWECKER, J ;
LEHN, JM ;
ZIESSEL, R .
HELVETICA CHIMICA ACTA, 1986, 69 (08) :1990-2012
[3]   EFFICIENT PHOTOCHEMICAL REDUCTION OF CO2 TO CO BY VISIBLE-LIGHT IRRADIATION OF SYSTEMS CONTAINING RE(BIPY)(CO)3X OR RU(BIPY)32+-CO2+ COMBINATIONS AS HOMOGENEOUS CATALYSTS [J].
HAWECKER, J ;
LEHN, JM ;
ZIESSEL, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (09) :536-538
[4]   A NEW PATHWAY FOR PHOTOBLEACHING OF [FAC-RE(2,2'-BIPYRIDINE)(CO)3BR] BY TRIETHYLAMINE - ETHYLATION OF THE BIPYRIDINE LIGAND [J].
ISHITANI, O ;
NAMURA, I ;
YANAGIDA, S ;
PAC, C .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (15) :1153-1154
[5]  
KALYANASUNDARAM K, 1986, J CHEM SOC F2, P2401
[6]   A MECHANISTIC INVESTIGATION OF THE PHOTOINDUCED REDUCTION OF CARBON-DIOXIDE MEDIATED BY TRICARBONYLBROMO(2,2'-BIPYRIDINE)RHENIUM(I) [J].
KUTAL, C ;
WEBER, MA ;
FERRAUDI, G ;
GEIGER, D .
ORGANOMETALLICS, 1985, 4 (12) :2161-2166
[7]   FURTHER-STUDIES OF THE PHOTOINDUCED REDUCTION OF CARBON-DIOXIDE MEDIATED BY TRICARBONYLBROMO(2,2'-BIPYRIDINE)RHENIUM(I) [J].
KUTAL, C ;
CORBIN, AJ ;
FERRAUDI, G .
ORGANOMETALLICS, 1987, 6 (03) :553-557
[8]   REMARKABLE SOLVENT EFFECTS ON THE PHOTOCATALYTIC BEHAVIOR OF [FAC-RE(2,2'-BIPYRIDINE)(CO)3BR] - SELECTIVE HYDROGEN EVOLUTION IN ETHER SOLVENTS IN THE PRESENCE OF TRIETHYLAMINE [J].
PAC, C ;
ISHII, K ;
YANAGIDA, S .
CHEMISTRY LETTERS, 1989, (05) :765-768
[9]   ONE-ELECTRON AND 2-ELECTRON PATHWAYS IN THE ELECTROCATALYTIC REDUCTION OF CO2 BY FAC-RE(2,2'-BIPYRIDINE)(CO)3CL [J].
SULLIVAN, BP ;
BOLINGER, CM ;
CONRAD, D ;
VINING, WJ ;
MEYER, TJ .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (20) :1414-1415
[10]   A NEW MECHANISM FOR PHOTOSUBSTITUTION OF ORGANOMETALLIC COMPLEXES - GENERATION OF SUBSTITUTIONALLY LABILE OXIDATION-STATES BY EXCITED-STATE ELECTRON-TRANSFER IN THE PRESENCE OF LIGANDS [J].
SUMMERS, DP ;
LUONG, JC ;
WRIGHTON, MS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (17) :5238-5241