ELECTROSYNTHESIS OF UNSYMMETRICAL DONOR-ACCEPTOR POLYARYLS

被引：15

作者：

BOY, P ^{[1
]}

COMBELLAS, C ^{[1
]}

THIEBAULT, A ^{[1
]}

AMATORE, C ^{[1
]}

JUTAND, A ^{[1
]}

机构：

[1] ECOLE NORMALE SUPER,CHIM LAB,F-75231 PARIS 05,FRANCE

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 04期

关键词：

DONOR-ACCEPTOR POLYARYLS; PALLADIUM COMPLEXES CATALYSIS; LIQUID AMMONIA; SRN1;

D O I：

10.1016/S0040-4039(00)93977-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Unsymmetrical Donor-Acceptor Polyaryls are synthesized by an electrochemically induced S(RN)1 reaction using 2,6-ditertbutyl phenoxide as nucleophile and acceptor substituted polyarylbromides. The latter are synthesized by a cross coupling reaction of aromatic organometallic reagents and aromatic halides catalyzed by palladium complexes.

引用

页码：491 / 494

页数：4

共 14 条

[1] THEORY AND EXPERIMENTAL ILLUSTRATION OF PREPARATIVE ELECTROCHEMISTRY USING REDOX CATALYSIS OF ELECTRON-TRANSFER INITIATED RADICAL CHAIN-REACTIONS - APPLICATION TO THE CROSS-COUPLING BETWEEN ARYL HALIDES AND PHENOXIDE IONS
ALAM, N
AMATORE, C
COMBELLAS, C
THIEBAULT, A
VERPEAUX, JN
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (26) : 6347 - 6356
[2] ELECTROCHEMICALLY CATALYZED AROMATIC NUCLEOPHILIC-SUBSTITUTION - PHENOXIDE ION AS NUCLEOPHILE
ALAM, N
AMATORE, C
COMBELLAS, C
PINSON, J
SAVEANT, JM
THIEBAULT, A
VERPEAUX, JN
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (07) : 1496 - 1504
[3] PHENOXIDE IONS AS NUCLEOPHILES IN SRN1 AROMATIC NUCLEOPHILIC-SUBSTITUTION
AMATORE, C
COMBELLAS, C
PINSON, J
SAVEANT, JM
THIEBAULT, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (01) : 7 - 8
[4] EFFICIENT PALLADIUM-CATALYZED SYNTHESIS OF UNSYMMETRICAL DONOR-ACCEPTOR BIARYLS AND POLYARYLS
AMATORE, C
JUTAND, A
NEGRI, S
FAUVARQUE, JF
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 390 (03) : 389 - 398
[5] HIGHLY POLARIZABLE ZWITTER-IONS FOR NONLINEAR OPTICS - SYNTHESIS, STRUCTURE AND PROPERTIES OF PHENOXIDE-PYRIDINIUM DERIVATIVES
BACQUET, G
BASSOUL, P
COMBELLAS, C
SIMON, J
THIEBAULT, A
TOURNILHAC, F
[J]. ADVANCED MATERIALS, 1990, 2 (6-7) : 311 - 313
[6] ADDITION OF ARYL RADICALS GENERATED FROM ELECTROCHEMICAL REDUCTION OF ARYL HALIDES ON CARBON-CARBON DOUBLE-BONDS
CHAMI, Z
GAREIL, M
PINSON, J
SAVEANT, JM
THIEBAULT, A
[J]. TETRAHEDRON LETTERS, 1988, 29 (06) : 639 - 642
[7] SELECTIVE ELECTROCHEMICAL AND PHOTOCHEMICAL SYNTHESES OF UNSYMMETRICAL BIARYLS AND THEIR NON-LINEAR OPTICAL-PROPERTIES
COMBELLAS, C
GAUTIER, H
SIMON, J
THIEBAULT, A
TOURNILHAC, F
BARZOUKAS, M
JOSSE, D
LEDOUX, I
AMATORE, C
VERPEAUX, JN
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (03) : 203 - 204
[8] FAUVARQUE JF, 1990, BF9003886 COMP GEN
[9] KATRITZKI AR, 1980, J CHEM SOC P1, V7, P2480
[10] NONLINEAR OPTICAL-PROPERTIES OF ASYMMETRIC POLYPHENYLS - EFFICIENCY VERSUS TRANSPARENCY TRADE-OFF
LEDOUX, I
ZYSS, J
JUTAND, A
AMATORE, C
[J]. CHEMICAL PHYSICS, 1991, 150 (01) : 117 - 123

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