VIBRATIONAL-SPECTRA OF CRYSTALS WITH THE A-TYPE RARE-EARTH OXIDE STRUCTURE .1. LA2O3 AND ND2O3

被引：63

作者：

BOLDISH, SI ^{[1
]}

WHITE, WB ^{[1
]}

机构：

[1] PENN STATE UNIV,MAT RES LAB,UNIVERSITY PK,PA 16802

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1979年 / 35卷 / 11期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0584-8539(79)80204-4

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Infrared reflectance measurements of Nd2O3 and single crystal Raman measurements of La2O3 and Nd2O3 were obtained. The A-type RE oxides belong to space group P3m1 and should have (2A1g + 2Eg) Raman + (2A2u + 2Eu) i.r. modes. The Raman spectra are in exact agreement with the predictions. The i.r. spectra of Nd2O3 are also in agreement with the factor group analysis with two rather strong bands for E|c and E⊥c, but in addition has weaker bands, possibly multiphonon bands, adjacent to the high-frequency bands. © 1979.

引用

页码：1235 / 1242

页数：8

共 20 条

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